电感耦合等离子体原子发射光谱法测定辛酸铑催化剂中铂钯铅铁铜铝镍

准确测定辛酸铑催化剂中杂质元素含量,是判定产品是否合格的重要指标之一。以往常采用直流电弧发射光谱法(摄谱法)进行检测,但测定周期长,且重复性较差。用电感耦合等离子体原子发射光谱法(ICP-AES)测定辛酸铑催化剂中微量杂质元素时,辛酸铑催化剂样品中含有的大量有机组分和铑基体会对测定有严重干扰。实验采用反复滴加硝酸消解样品中有机组分,再用王水溶解盐类,选用合适背景点扣除的方式消除铑基体的干扰,建立了使用ICP-AES测定辛酸铑催化剂中0.001%~0.1%(质量分数)Pt、Pd、Pb、Fe、Cu、Al、Ni等7种微量杂质元素的方法。各元素在0.10~10.00μg/mL范围内与其发射强度呈线性关系,相关系数均大于0.9999;方法检出限(μg/mL)为0.075(Pt)、0.0033(Pd)、0.015(Pb)、0.0036(Fe)、0.010(Cu)、0.001(Al)、0.012(Ni)。实验方法用于测定辛酸铑催化剂样品中Pt、Pd、Pb、Fe、Cu、Al、Ni,结果的相对标准偏差为(RSD,n=7)为1.4%~9.6%。按照实验方法测定辛酸铑催化剂中Pt、Pd、Pb、Fe、Cu、Al、Ni,并与直流电弧发射光谱法的测定结果进行比对,结果相一致。     

Q700D热影响粗晶区疲劳寿命与小裂纹扩展分析

摘要：为提高焊接构件的动载疲劳寿命，以热模拟为试验手段，对Q700D高强钢进行了焊接热模拟，研究了粗晶热影响区的疲劳寿命、小裂纹扩展行为以及组织软化特征。利用Paris方程和轴向拉伸疲劳试验数据，建立了ΔKth值与模拟粗晶区疲劳寿命的对应关系，利用ΔKth值实现了快速预估粗晶区疲劳寿命。研究表明：相同应力幅值下的lgN值与ΔKth值存在一定的线性拟合关系，即ΔKth值越大，则疲劳寿命N越长。小裂纹扩展微观机理在于所形成的大角度晶界（不小于15°）对小裂纹尖端的止裂性较强，可迫使小裂纹尖端转向耗能。CGHAZ的软化与第二相粒子回熔与粗化有关，粗化的第二相粒子易萌生小裂纹，可通过提高大角度晶界抑制裂纹扩展。     

Corrosion protection of aluminum alloy by epoxy coatings containing polyaniline modified graphene additives

In the study, polyaniline/reduced‐graphene oxide (PANI‐RGO) composites, fabricated by loading 2, 5, and 8wt% graphene oxide, was prepared by in‐situ emulsion polymerization and reduction. They are characterized by Fourier transform infrared spectroscopy, X‐ray diffraction, and scanning electron microscopy. Epoxy coatings adding PANI and PANI‐RGO composites were coated on the surface of AA5083 Al alloy. The anticorrosion performance of the coatings is measured by electrochemical impedance spectroscopy and potentiodynamic polarization curve in 3.5wt% NaCl solution. The results demonstrate that the epoxy/PANI‐RGO coating exhibits a better protection against AA5083 alloy corrosion compared with the epoxy/PANI coating. Enhancement of the passivation performance of PANI was obtained by the addition of RGO into epoxy/PANI coating system.     

Development of microbially influenced corrosion on carbon steel in a simulated water injection system

Microbially influenced corrosion (MIC) on internal pipeline surfaces has become a severe problem during the water injection process in secondary oil recovery. The formation of a biofilm, normally dominated by sulfate‐reducing bacteria (SRB), is believed to be the critical step of the MIC process. A continuously fed biofilm simulating the water injection process was operated to investigate the influence of biofilm development on MIC behavior in the early phase of corrosion development. The development of the corrosion product film and biofilm was monitored for 5 months with electrochemical impedance spectroscopy, linear polarization resistance, scanning electron microscopy, 3D optical profiling, and direct weight measurement. MIC development was found to comprise three phases: initialization, transition, and stabilization. The initialization phase involved the formation of the corrosion product layer and the initial attachment of the sessile microbes on metal surface. In the transition phase, the MIC process gradually shifted from charge‐transfer‐controlled reaction to diffusion‐controlled reaction. The stabilization phase featured mature and compact biofilm on the metal surface, and the general corrosion rate (CR) decreased due to the diffusional effect, while the pitting CR was enhanced at a lower carbon source level, which supported the mechanism of direct electron uptake from the metal surface by SRB.     

基于证据权模型的赤峰—呼伦贝尔成矿带找矿预测

赤峰—呼伦贝尔成矿带是大兴安岭南部黄岗梁—甘珠尔庙成矿带的一部分，该区域地质构造复杂，地壳以及岩浆岩活动剧烈，在大兴安岭南部区域矿带中形成了多金属矿产成矿潜力。为寻求研究区找矿突破，解决赤峰—呼伦贝尔成矿带的成矿预测理论以及模型预测不完善的问题，提出了一种基于地理信息系统技术和数据权理论的赤峰—呼伦贝尔成矿带找矿预测模型。首先阐述了该预测模型的构建思路，利用地理信息系统空间分析软件（ArcGIS）对获取的研究区域地层信息、构造信息、岩浆岩信息进行空间分析，形成空间数据库；然后将证据权理论应用于预测模型中，构建了赤峰—呼伦贝尔成矿带成矿预测模型。根据构建的模型，进行了成矿预测，通过将空间数据库中的数据代入预测模型中得到该区域内各证据因子的权重以及概率，进而将该区域按照成矿潜力分成3类靶区。经验证，各靶区找矿潜力较好，证明了预测结果的有效性。所构建的成矿预测模型，对于进一步在赤峰—呼伦贝尔成矿带进行找矿勘探研究与实践具有一定的参考价值。     

Experimental investigation of different morphology textured ceramic tools by in-situ formed for the dry cutting

Surface texture is considered an important measure to improve the cutting performance of a tool. In this study, we have prepared three types of textured and conventional tools on the rake face by an in-situ formed method. During the experiment, the best parameters of three types of textured tools were selected for dry cutting AISI 1045 steel at different cutting speeds. Cutting forces, cutting temperatures, workpiece surface roughness, and tool wear were measured during the cutting process. The results showed that textured tools have significantly reduced cutting force, cutting temperature, and tool wear, and the roughness of the workpiece was improved compared with the conventional tool. The micro-pit texture tool has less stress contact region than the micro-groove width texture tool, but the micro-groove width texture tool exhibiting the best cutting performance. This investigation clearly showed that the textured tool prepared by the in-situ formed method has improved cutting performance.     

内蒙古阿巴嘎旗更新世阿巴嘎组火山岩岩石化学特征及成因

阿巴嘎旗位于内蒙古中东部，区内广泛发育上更新统阿巴嘎组。通过对区内火山岩岩石地球化学特征及其成因进行分析，结果表明：岩石组合由橄榄玄武岩、伊丁石化玄武岩和少量火山碎屑岩组成；岩石具有富钛，富镁，钠高钾低的特点，岩浆结晶分异程度较低，岩浆物质来源较深，其物源具有幔源成因的特点；该套火山岩为板内玄武岩。     

Combustion Wave Propagation of a Modular Porous Burner with Annular Heat Recirculation

A numerical investigation of the different arrangements of porous media in a combustor with annular heat recirculation is conducted.The effect of annular heat recirculation and porous block arrangement on the characteristics of combustion wave propagation is numerically studied.Results show that power input,heat capacity of porous matrix,arrangement of porous blocks,and annular heat recirculation are major factors that influence the propagation of combustion wave.The overall temperature of ceramic porous burner is higher than that of ceramic-metal type burner due to the lower heat storage capacity of the former,especially for the temperature downstream.The flame temperature is higher upstream and lower downstream with metal foams in the annulus than that without metal foams.The flame temperature of uniformity type burner is more uniform than that of gradually-varied and modular type burners.The flame front moves more slowly with metal foams in the annulus than that without metal foams due to the better preheating effect of metal foams.The flame position moves downstream,and the flame temperature gradually decreases and is eventually extinguished due to the low preheating temperature.     

基于临界钙矾石膨胀破坏的磷石膏基复合胶凝材料的配料计算研究

为制备大掺量磷石膏基复合胶凝材料,在确定主要水化产物类型的基础上,通过计算临界钙矾石膨胀破坏的边界条件,确定各组分最佳掺量范围,研究其对复合胶凝材料力学性能、干缩性能的影响,并通过X射线衍射（XRD）、扫描电镜（SEM）等测试方法研究水化产物的组成及发展规律。研究结果表明：通过理论配料计算,矿粉掺量为50%（质量分数）时,最大磷石膏掺量为26.3%（质量分数）,最小熟料掺量为23.6%（质量分数）。最佳配比组28 d胶砂抗压强度为45.2 MPa,线膨胀率小于0.04%;对比组28 d抗压强度仅有36.4 MPa,线膨胀率远大于0.04%。XRD、SEM表征结果表明,磷石膏基复合胶凝材料的水化产物主要是钙矾石（AFt）和水化硅酸钙（C-S-H）凝胶,氢氧化钙几乎反应完全;对比组钙矾石生成量远大于最佳配料组,微观结构存在大量裂缝。这说明理论配料计算可以有效用于磷石膏基复合胶凝材料的配比优化。